Aluminum chloride

What is Aluminum chloride

**Introduction to Aluminium Trichloride (AlCl₃)** Aluminium trichloride (AlCl₃) is a versatile inorganic compound widely used in industrial and chemical applications. It exists as a white crystalline solid in its anhydrous form and as a hexahydrate (AlCl₃·6H₂O) when hydrated. Anhydrous AlCl₃ is highly hygroscopic and acts as a strong Lewis acid, making it a key catalyst in Friedel-Crafts alkylation and acylation reactions in organic synthesis. It is also employed in the production of dyes, pharmaceuticals, and petrochemicals. Additionally, AlCl₃ serves as an electrolyte in aluminium refining and as a flocculant in water treatment. Due to its reactivity, proper handling is essential to avoid moisture exposure and ensure safety.

Preparation Process: Aluminium trichloride (AlCl₃) can be prepared by reacting aluminium metal with chlorine gas at high temperatures (around 650–750°C). The reaction proceeds as: **2Al + 3Cl₂ → 2AlCl₃** Alternatively, it can be synthesized by reacting aluminium oxide (Al₂O₃) with carbon and chlorine at 800–900°C: **Al₂O₃ + 3C + 3Cl₂ → 2AlCl₃ + 3CO** For anhydrous AlCl₃, the product is sublimed and collected in a cooled receiver. Hydrated forms are obtained by dissolving aluminium hydroxide in hydrochloric acid, followed by crystallization: **Al(OH)₃ + 3HCl → AlCl₃·6H₂O**. Handling requires dry conditions to prevent hydrolysis.

Usage Scenarios: Aluminium trichloride (AlCl₃) is primarily used as a catalyst in Friedel-Crafts reactions for alkylation and acylation in organic synthesis, enabling the formation of carbon-carbon bonds. It is also employed in the production of dyes, pharmaceuticals, and fragrances. In the petrochemical industry, AlCl₃ aids in refining processes like isomerization and polymerization. Additionally, it serves as a Lewis acid in inorganic and organometallic reactions. Other applications include its use in the manufacture of ethylbenzene and detergents. In metallurgy, it acts as a flux for aluminum. AlCl₃ is also utilized in water treatment and as an antiperspirant ingredient in personal care products.

Aluminum chloride Basic Info

Chemical Name Aluminum chloride

Synonyms AlCl3;ALUMINIUM CHLORIDE;ALUMINIUM TRICHLORIDE;ALUMINUM TRICHLORIDE;Aluminiumchlorid;ALUMINIUM CLORIDE;Aluminum chloride, anhydrous;Aluminium chloride, anhydrous, powder, extra pure, 98.5%;Pearsall;NSC 143016

CAS No. 7446-70-0

Molecular Formula AlCl3

Molecular Weight 133.34

PSA 0.00000

LogP 2.06850

Safely Info

RTECS BD0525000

Hazard Class 8

Safety Statements 26-45-28-7/8-36/37/39-61-23-28A-53

HS Code 28273200

WGK Germany -

Packing Group II

RIDADR UN 3264 8/PG 3

Risk Statements 36/38-34-62-51/53-48/23/24-40-23/24/25-14-48/25-48/20-52-36/37/38-52/53-48/23/24/25-60

Hazard Codes C,Xi,T

Caution Statement P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363

Hazard Declaration H314

Symbol GHS05

Signal Word Danger

Aluminum chloride Price

Here is a rough price range for aluminium trichloride (AlCl₃) in the listed countries. Note that prices can vary based on purity, quantity, and market conditions. If no specific data is available, "No results" is indicated:

1. **United States**: $1.50 - $3.00 per kg
2. **China**: $0.80 - $2.00 per kg
3. **Russia**: $1.20 - $2.50 per kg
4. **Germany**: $1.80 - $3.50 per kg
5. **India**: $0.90 - $2.20 per kg
6. **Japan**: $2.00 - $4.00 per kg
7. **Brazil**: $1.50 - $3.00 per kg
8. **South Korea**: $1.70 - $3.20 per kg
9. **Philippines**: No results
10. **United Kingdom**: $2.00 - $4.00 per kg
11. **France**: $1.90 - $3.50 per kg
12. **Mexico**: $1.50 - $3.00 per kg
13. **Canada**: $1.80 - $3.50 per kg
14. **South Africa**: $1.50 - $3.00 per kg
15. **Egypt**: No results
16. **Turkey**: $1.20 - $2.50 per kg
17. **Thailand**: $1.00 - $2.50 per kg
18. **Indonesia**: $1.00 - $2.50 per kg

*Prices are approximate and may vary based on supplier, quantity, and market conditions.*

MSDS

Name:	Aluminum chloride anhydrous granules 99% Material Safety Data Sheet
Synonym:	Trichloroaluminum; Aluminum trichloride
CAS:	7446-70-0

Section 1 - Chemical Product MSDS Name:Aluminum chloride anhydrous granules 99% Material Safety Data Sheet
Synonym:Trichloroaluminum; Aluminum trichloride

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
7446-70-0	Aluminum chloride	99	231-208-1

Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.Corrosive.Hygroscopic.Water-Reactive.
Potential Health Effects
Eye:
Causes severe eye burns.
Skin:
Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
Ingestion:
Causes gastrointestinal tract burns. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract.
Inhalation:
Causes delayed lung injury. Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma.
Chronic:
Aluminum may be implicated in Alzheimer's disease. Inhalation of aluminum containing dusts may cause pulmonary disease.

Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Use water with caution and in flooding amounts. Containers may explode when heated or if contaminated with water. Aluminum chloride reacts violently with water producing hydrochloric acid and heat. Hydrochloric acid solutions react with most metals, forming flammable hydrogen gas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER! Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out. For large fires flood fire with water from a distance.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Do not expose spill to water.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Loosen closure cautiously before opening. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Do not allow contact with water.
Storage:
Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from water. Corrosives area.
Loosen closure cautiously before opening. Separate from organic materials.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear chemical goggles and a face shield.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective gloves to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Appearance: yellow-beige or gray
Odor: Strong acid odor.
pH: Not available.
Vapor Pressure: 1 mm Hg @ 100C
Viscosity: Not available.
Boiling Point: 181 deg C (sublimes)
Freezing/Melting Point: 194 deg C @ 5.2atm
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 2.4400g/cm3
Molecular Formula: AlCl3
Molecular Weight: 133.34

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Aluminum chloride reacts violently with water producing hydrochloric acid and heat., organic materials.
Hazardous Decomposition Products:
Hydrogen chloride, aluminum oxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7446-70-0: BD0525000 LD50/LC50:
CAS# 7446-70-0: Oral, mouse: LD50 = 1130 mg/kg; Oral, rat: LD50 = 3450 mg/kg; Skin, rabbit: LD50 = >2 gm/kg.
Carcinogenicity:
Aluminum chloride - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: ALUMINIUM CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1726
Packing Group: II
IMO
Shipping Name: ALUMINIUM CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1726
Packing Group: II
RID/ADR
Shipping Name: ALUMINIUM CHLORIDE, ANHYDROUS
Dangerous Goods Code: 8(11B)
UN Number: 1726

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7446-70-0: 1
United Kingdom Occupational Exposure Limits
CAS# 7446-70-0: OES-United Kingdom, TWA (listed as ** undefined
**): total inhalable dust: 10 mg/m3 TWA; respirable dust: 4 mg/m3
TWA
Canada
CAS# 7446-70-0 is listed on Canada's DSL List.
CAS# 7446-70-0 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 7446-70-0: OEL-AUSTRALIA:TWA 2 mg(Al)/m3
OEL-BELGIUM:TWA 2 mg(Al)/m3
OEL-DENMARK:TWA 2 mg(Al)/m3
OEL-FRANCE:TWA 2 mg(Al)/m3
OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3
OEL-RUSSIA:TWA 2 mg(Al)/m3
OEL-SWEDEN:TWA 2 mg(Al)/m3
OEL-SWITZERLAND:TWA 2 mg(Al)/m3
OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 7446-70-0 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
N/A

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1.Identification

1.1 GHS Product identifier

Product name	aluminium trichloride

1.2 Other means of identification

Product number	-
Other names	Aluminium chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

Company	MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address	Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road, Xuhui District, Shanghai, China
Telephone	+86(21)64956998
Fax	+86(21)54365166

1.5 Emergency phone number

Emergency phone number	+86-400-6021-666
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Skin corrosion, Category 1B

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Danger
Hazard statement(s)	H314 Causes severe skin burns and eye damage
Precautionary statement(s)
Prevention	P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response	P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P363 Wash contaminated clothing before reuse. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310 Immediately call a POISON CENTER/doctor/… P321 Specific treatment (see ... on this label). P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage	P405 Store locked up.
Disposal	P501 Dispose of contents/container to ...

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name	Common names and synonyms	CAS number	EC number	Concentration
aluminium trichloride	aluminium trichloride	7446-70-0	none	100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms/effects, acute and delayed

no data available

4.3 Indication of immediate medical attention and special treatment needed, if necessary

no data available

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Specific hazards arising from the chemical

no data available

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state	no data available
Colour	no data available
Odour	no data available
Melting point/ freezing point	-50°C(lit.)
Boiling point or initial boiling point and boiling range	156°C
Flammability	no data available
Lower and upper explosion limit / flammability limit	no data available
Flash point	88°C
Auto-ignition temperature	no data available
Decomposition temperature	no data available
pH	no data available
Kinematic viscosity	no data available
Solubility	no data available
Partition coefficient n-octanol/water (log value)	no data available
Vapour pressure	no data available
Density and/or relative density	1.249g/mLat 25°C
Relative vapour density	no data available
Particle characteristics	no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

no data available

10.6 Hazardous decomposition products

no data available

11.Toxicological information

Acute toxicity

Oral: no data available
Inhalation: no data available
Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

Toxicity to fish: no data available
Toxicity to daphnia and other aquatic invertebrates: no data available
Toxicity to algae: no data available
Toxicity to microorganisms: no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: UN1726

IMDG: UN1726

IATA: UN1726

14.2 UN Proper Shipping Name

ADR/RID: ALUMINIUM CHLORIDE, ANHYDROUS

IMDG: ALUMINIUM CHLORIDE, ANHYDROUS

IATA: ALUMINIUM CHLORIDE, ANHYDROUS

14.3 Transport hazard class(es)

ADR/RID: 8

IMDG: 8

IATA: 8

14.4 Packing group, if applicable

ADR/RID: II

IMDG: II

IATA: II

14.5 Environmental hazards

ADR/RID: no

IMDG: no

IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name	Common names and synonyms	CAS number	EC number
aluminium trichloride	aluminium trichloride	7446-70-0	none
European Inventory of Existing Commercial Chemical Substances (EINECS)			Listed.
EC Inventory			Listed.
United States Toxic Substances Control Act (TSCA) Inventory			Listed.
China Catalog of Hazardous chemicals 2015			Listed.
New Zealand Inventory of Chemicals (NZIoC)			Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)			Listed.
Vietnam National Chemical Inventory			Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)			Listed.

16.Other information

Information on revision

Creation Date	Aug 12, 2017
Revision Date	Aug 12, 2017

Abbreviations and acronyms

CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%

References

IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.

Aluminum chloride Suppliers

Company Name

Business Type

Location

Details

Nanjing Ming Shilin International Trade Co., Ltd.

Trader

China Jiangsu Nanjing

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Shandong Kunbao Chemical Co., Ltd.

Trader

China Shandong Dongying

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Shandong Kehao Chemical Technology Co., Ltd.

Trader

China Shandong Zibo

Request For Quotation

Jinan scene chemical co., LTD

Trader

China Shandong Jinan

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Luohe Yuanjian Fine Chemical Co., Ltd.

Trader

China Henan Luohe

Request For Quotation

Qianjiang City Industry and Chemicals Co., Ltd.

Trader

China Hubei Qianjiang

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Shandong zhishang chemical Co.,Ltd

China Shandong Jinan

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MALAYSIA CHEMICAL SUPPLIES

Malaysia

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Farmasino Pharmaceutical

China Jiangsu Nanjing

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Wuhan Golden Wing Industry & Trade Co.,Ltd.

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What is Aluminum chloride

Aluminum chloride Basic Info

Safely Info

Aluminum chloride Price

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